Elimination Reactions of Alcohols | 食品添加物合法業者資訊網
2015年4月16日—Allabouteliminationofalcoholsusingstrongacidswithnon-nucleophiliccounterions,suchasH2SO4,H3PO4,andTsOH.
All About Elimination Reactions of Alcohols (With Acid)
The hydroxyl group of alcohols is normally a poor leaving group. However, when treated with strong acid, R-OH is converted into R-OH2(+) and H2O is a much better leaving group. With tertiary alcohols, H2O can then leave, resulting in a carbocation. If a strong acid such as H2SO4 or p-TsOH is used, the most likely result is elimination, since the conjugate bases of these acids (HSO4– and TsO– ) are poor nucleophiles and unlikely to add to the carbocation.Table of Contents
Hydrohalic Acids (HX) Plus Alcohols Give Substitution Products…[1] …But H2SO4, H3PO4, and TsOH Give Elimination Products![2] Elimination of Tertiary Alcohols Proceeds Through an E1 Mechanism[3] Why Do H2SO4, H3PO4 and TsOH Give Elimination Products? [4] What About Secondary Alcohols?[5] Elimination Reactions With Carbocation Rearrangements[6] Ring Expansion Followed By Elimination[7] Primary Alcohols and H2SO...p | 食品添加物合法業者資訊網
Elimination Reactions of Alcohols | 食品添加物合法業者資訊網
Illustrated Glossary of Organic Chemistry | 食品添加物合法業者資訊網
TsOH | 食品添加物合法業者資訊網
Article Catalytic Systems Containing p | 食品添加物合法業者資訊網
Transition‐Metal‐Free | 食品添加物合法業者資訊網
[Reaction of 3 | 食品添加物合法業者資訊網
Ch17 | 食品添加物合法業者資訊網
Fischer Esterification | 食品添加物合法業者資訊網
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